Suitable factors of preparation of intermediate product potassium hydrogen sulfate and neutralizing reaction of potassium hydrogen sulfate with ammonia is given. 用硫酸锆、硫酸氢钾分别代替浓硫酸,催化环己醇脱水合成了环己烯,主要考察了催化剂用量、分馏反应时间对产物收率的影响。
The yield of cyclohexene was 68.29% with zirconium sulfate as catalyst and fractionation reaction for 60 min. The property of repeat utilization of zirconium sulfate was better than that of potassium hydrogen sulfate. 其中硫酸锆催化效果更好,在最佳用量下,分馏反应60min,产物收率可达68.29%,且催化剂的重复使用性能较好。
The low temperature dilute acid process of potassium hydrogen sulfate 硫酸氢钾低温稀酸新工艺